C4-symmetric alkoxyresorcin[4]arene triflates: The use of palladium-catalyzed reactions in the synthesis of axially chiral derivatives with amino- and/or alkoxy-substituents

Bulman Page, Philip C., Bygrave, Terence R., Chan, Yohan, Heaney, Harry and McKee, Vickie (2011) C4-symmetric alkoxyresorcin[4]arene triflates: The use of palladium-catalyzed reactions in the synthesis of axially chiral derivatives with amino- and/or alkoxy-substituents. European Journal of Organic Chemistry, 2011 (16). pp. 3016-3025. ISSN 1434-193X

Full text not available from this repository. (Request a copy)

Abstract

The conversion of axially chiral tetraalkoxyresorcin[4]arenes (cyclochiral resorcinarenes) into the related tetrakis(triflates) in high yields is described; this provides an efficient source of chiral materials for use in palladium-catalyzed transformations, including the reductive removal of triflate groups and the synthesis of compounds that are formally derived from 3-aminophenol, providing axially chiral derivatives that are nitrogen-substituted on the upper rim.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User: Rachel Smith
Date Deposited: 16 Feb 2012 11:37
Last Modified: 17 Jan 2024 01:20
URI: https://ueaeprints.uea.ac.uk/id/eprint/37148
DOI: 10.1002/ejoc.201100122

Actions (login required)

View Item View Item