C4-symmetric alkoxyresorcin[4]arene triflates: The use of palladium-catalyzed reactions in the synthesis of axially chiral derivatives with amino- and/or alkoxy-substituents

Bulman Page, Philip C., Bygrave, Terence R., Chan, Yohan, Heaney, Harry and McKee, Vickie (2011) C4-symmetric alkoxyresorcin[4]arene triflates: The use of palladium-catalyzed reactions in the synthesis of axially chiral derivatives with amino- and/or alkoxy-substituents. European Journal of Organic Chemistry, 2011 (16). pp. 3016-3025. ISSN 1434-193X

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Abstract

The conversion of axially chiral tetraalkoxyresorcin[4]arenes (cyclochiral resorcinarenes) into the related tetrakis(triflates) in high yields is described; this provides an efficient source of chiral materials for use in palladium-catalyzed transformations, including the reductive removal of triflate groups and the synthesis of compounds that are formally derived from 3-aminophenol, providing axially chiral derivatives that are nitrogen-substituted on the upper rim.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	16 Feb 2012 11:37
Last Modified:	24 Sep 2024 09:02
URI:	https://ueaeprints.uea.ac.uk/id/eprint/37148
DOI:	10.1002/ejoc.201100122

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