Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold
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ToolsNieto-Oberhuber, Cristina, López, Salomé, Munoz-Herranz, Maria, Cárdenas, Diego J., Buñuel, Elena, Nevado, Cristina and Echavarren, Antonio M. (2005) Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold. Angewandte Chemie-International Edition, 44 (38). pp. 6146-6148. ISSN 1433-7851
Full text not available from this repository. (Request a copy)Abstract
Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Related URLs: | |
| Depositing User: | Rachel Smith |
| Date Deposited: | 14 Feb 2012 16:20 |
| Last Modified: | 21 Apr 2020 20:07 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/37112 |
| DOI: | 10.1002/anie.200501937 |
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