Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold

Nieto-Oberhuber, Cristina, López, Salomé, Munoz-Herranz, Maria, Cárdenas, Diego J., Buñuel, Elena, Nevado, Cristina and Echavarren, Antonio M. (2005) Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold. Angewandte Chemie International Edition, 44 (38). pp. 6146-6148. ISSN 1433-7851

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Abstract

Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	14 Feb 2012 16:20
Last Modified:	13 Oct 2025 23:35
URI:	https://ueaeprints.uea.ac.uk/id/eprint/37112
DOI:	10.1002/anie.200501937

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