Microporous poly(tri(4-ethynylphenyl)amine) networks: Synthesis, properties, and atomistic simulation

Jiang, Jia-Xing, Trewin, Abbie, Su, Fabing, Wood, Colin D., Niu, Hongjun, Jones, James T. A., Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128 and Cooper, Andrew I. (2009) Microporous poly(tri(4-ethynylphenyl)amine) networks: Synthesis, properties, and atomistic simulation. Macromolecules, 42 (7). pp. 2658-2666. ISSN 0024-9297

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Abstract

Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m2/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Pharmacy (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Pharmaceutical Materials and Soft Matter Faculty of Science > Research Groups > Drug Delivery and Pharmaceutical Materials (former - to 2017)
Depositing User:	Rhiannon Harvey
Date Deposited:	31 Jan 2012 11:52
Last Modified:	24 Sep 2024 09:19
URI:	https://ueaeprints.uea.ac.uk/id/eprint/36616
DOI:	10.1021/ma802625d

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