Ingleson, MJ, Barrio, JP, Bacsa, J, Steiner, A, Darling, GR, Jones, JTA, Khimyak, YZ ORCID: https://orcid.org/0000-0003-0424-4128 and Rosseinsky, MJ
(2009)
Magnesium Borohydride Confined in a Metal-Organic Framework: A Preorganized System for Facile Arene Hydroboration.
Angewandte Chemie International Edition, 48 (11).
pp. 2012-2016.
ISSN 1521-3773
Abstract
In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Pharmacy |
Depositing User: | Rhiannon Harvey |
Date Deposited: | 31 Jan 2012 11:49 |
Last Modified: | 23 Oct 2022 01:52 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/36615 |
DOI: | 10.1002/anie.200804196 |
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