Magnesium Borohydride Confined in a Metal-Organic Framework: A Preorganized System for Facile Arene Hydroboration

Ingleson, MJ, Barrio, JP, Bacsa, J, Steiner, A, Darling, GR, Jones, JTA, Khimyak, YZ ORCID: https://orcid.org/0000-0003-0424-4128 and Rosseinsky, MJ (2009) Magnesium Borohydride Confined in a Metal-Organic Framework: A Preorganized System for Facile Arene Hydroboration. Angewandte Chemie International Edition, 48 (11). pp. 2012-2016. ISSN 1521-3773

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Abstract

In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Pharmacy
Depositing User:	Rhiannon Harvey
Date Deposited:	31 Jan 2012 11:49
Last Modified:	23 Oct 2022 01:52
URI:	https://ueaeprints.uea.ac.uk/id/eprint/36615
DOI:	10.1002/anie.200804196

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