Magnesium borohydride confined in a metal-organic framework: A preorganized system for facile arene hydroboration

Ingleson, Michael J., Barrio, Jorge Perez, Bacsa, John, Steiner, Alexander, Darling, George R., Jones, James T. A., Khimyak, Yaroslav Z. and Rosseinsky, Matthew J. (2009) Magnesium borohydride confined in a metal-organic framework: A preorganized system for facile arene hydroboration. Angewandte Chemie-International Edition, 48 (11). pp. 2012-2016. ISSN 1521-3773

Full text not available from this repository.

Abstract

In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.

Item Type:	Article
Additional Information:	This work was supported by EPSRC grant number EP/C511794
Faculty \ School:	Faculty of Science > School of Pharmacy (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Pharmaceutical Materials and Soft Matter Faculty of Science > Research Groups > Drug Delivery and Pharmaceutical Materials (former - to 2017)
Depositing User:	Rhiannon Harvey
Date Deposited:	31 Jan 2012 11:49
Last Modified:	06 Feb 2025 02:11
URI:	https://ueaeprints.uea.ac.uk/id/eprint/36615
DOI:	10.1002/anie.200804196

Actions (login required)

View Item