Magnesium borohydride confined in a metal-organic framework: A preorganized system for facile arene hydroboration

Ingleson, Michael J., Barrio, Jorge Perez, Bacsa, John, Steiner, Alexander, Darling, George R., Jones, James T. A., Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128 and Rosseinsky, Matthew J. (2009) Magnesium borohydride confined in a metal-organic framework: A preorganized system for facile arene hydroboration. Angewandte Chemie-International Edition, 48 (11). pp. 2012-2016. ISSN 1521-3773

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Abstract

In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.

Item Type:	Article
Additional Information:	This work was supported by EPSRC grant number EP/C511794
Faculty \ School:	Faculty of Science > School of Pharmacy (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Pharmaceutical Materials and Soft Matter Faculty of Science > Research Groups > Drug Delivery and Pharmaceutical Materials (former - to 2017)
Depositing User:	Rhiannon Harvey
Date Deposited:	31 Jan 2012 11:49
Last Modified:	24 Sep 2024 09:19
URI:	https://ueaeprints.uea.ac.uk/id/eprint/36615
DOI:	10.1002/anie.200804196

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