Palladium nanoparticle incorporation in conjugated microporous polymers by supercritical fluid processing

Hasell, Tom, Wood, Colin D., Clowes, Rob, Jones, James T. A., Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128, Adams, Dave J. and Cooper, Andrew I. (2010) Palladium nanoparticle incorporation in conjugated microporous polymers by supercritical fluid processing. Chemistry of Materials, 22 (2). pp. 557-564. ISSN 0897-4756

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Abstract

Palladium nanoparticles have been dispersed uniformly throughout a microporous poly(aryleneethynylene) material by the infusion of a CO2-soluble Pd precursor. The resulting composite has good thermal stability and has potential applications for example in heterogeneous catalysis. The porosity of the polymeric support was maintained after inclusion of the metal and the hydrogen uptake at room temperature was increased with respect to the unloaded porous support.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Pharmacy
UEA Research Groups:	Faculty of Science > Research Groups > Pharmaceutical Materials and Soft Matter Faculty of Science > Research Groups > Drug Delivery and Pharmaceutical Materials (former - to 2017)
Depositing User:	Rhiannon Harvey
Date Deposited:	31 Jan 2012 11:02
Last Modified:	22 Dec 2022 14:31
URI:	https://ueaeprints.uea.ac.uk/id/eprint/36606
DOI:	10.1021/cm9030446

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