New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes

Bulman Page, P. C. B., Farah, M. M., Buckley, B. R. and Blacker, A. J. (2007) New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes. The Journal of Organic Chemistry, 72 (12). pp. 4424-4430. ISSN 0022-3263

Full text not available from this repository. (Request a copy)

Abstract

A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%.

Item Type: Article
Uncontrolled Keywords: cis-olefins,enantioselective olefin epoxidation,oxaziridinium salt,in-situ,oxone,dioxirane,terminal olefins,oxygen-transfer,cinnamic acid-derivatives,amine-catalyzed epoxidation
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 20 Jun 2011 11:44
Last Modified: 21 Apr 2020 19:20
URI: https://ueaeprints.uea.ac.uk/id/eprint/32886
DOI: 10.1021/jo070255w

Actions (login required)

View Item View Item