New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes

Bulman Page, P. C. B., Farah, M. M., Buckley, B. R. and Blacker, A. J. (2007) New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes. The Journal of Organic Chemistry, 72 (12). pp. 4424-4430. ISSN 0022-3263

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Abstract

A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%.

Item Type:	Article
Uncontrolled Keywords:	cis-olefins,enantioselective olefin epoxidation,oxaziridinium salt,in-situ,oxone,dioxirane,terminal olefins,oxygen-transfer,cinnamic acid-derivatives,amine-catalyzed epoxidation
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	20 Jun 2011 11:44
Last Modified:	24 Sep 2024 09:39
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32886
DOI:	10.1021/jo070255w

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