Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison

Goncalves, Maria-Héléna, Martinez, Alexandre, Grass, Stéphane, Bulman Page, Philip C. and Lacour, Jérôme (2006) Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison. Tetrahedron Letters, 47 (30). pp. 5297-5301. ISSN 0040-4039

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Abstract

Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (+)-(S,S)-L-acetonamine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 83%).

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 20 Jun 2011 15:38
Last Modified: 21 Apr 2020 19:43
URI: https://ueaeprints.uea.ac.uk/id/eprint/32872
DOI: 10.1016/j.tetlet.2006.05.132

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