Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison

Goncalves, Maria-Héléna, Martinez, Alexandre, Grass, Stéphane, Bulman Page, Philip C. and Lacour, Jérôme (2006) Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison. Tetrahedron Letters, 47 (30). pp. 5297-5301. ISSN 0040-4039

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Abstract

Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (+)-(S,S)-L-acetonamine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 83%).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	20 Jun 2011 15:38
Last Modified:	24 Sep 2024 09:48
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32872
DOI:	10.1016/j.tetlet.2006.05.132

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