Synthesis of the first chiral, functionalised-bridged resorcinarenes in asymmetric catalysis: Evidence for intracavity asymmetric catalysis

Arnott, Gareth, Heaney, Harry, Hunter, Roger and Bulman Page, Philip C. (2004) Synthesis of the first chiral, functionalised-bridged resorcinarenes in asymmetric catalysis: Evidence for intracavity asymmetric catalysis. European Journal of Organic Chemistry (24). pp. 5126-5134. ISSN 1434-193X

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Abstract

Methodology is presented for synthesis of the first examples of chiral, bridged resorcinarenes with functionality in the bridge as possible sites for intracavity asymmetric catalysis. A preliminary study comparing unfunctionalised with functionalised lines using the enantio selective addition of diethylzinc to benzaldehyde as a probe reaction, provides compelling evidence for intracavity catalysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Jun 2011 09:48
Last Modified:	24 Sep 2024 10:02
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32854
DOI:	10.1002/ejoc.200400615

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