Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Bulman Page, Philip C., Vahedi, Hooshang, Bethell, Donald and Barkley, James V. (2003) Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives. Synthetic Communications, 33 (11). pp. 1937-1941. ISSN 0039-7911

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Abstract

DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

Item Type: Article
Uncontrolled Keywords: hydrogen-peroxide,dbu,nucleophile,sulfides,catalytic asymmetric oxidation
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jun 2011 09:42
Last Modified: 21 Apr 2020 20:29
URI: https://ueaeprints.uea.ac.uk/id/eprint/32851
DOI: 10.1081/scc-120020208

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