Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Bulman Page, Philip C., Vahedi, Hooshang, Bethell, Donald and Barkley, James V. (2003) Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives. Synthetic Communications, 33 (11). pp. 1937-1941. ISSN 0039-7911

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Abstract

DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

Item Type:	Article
Uncontrolled Keywords:	hydrogen-peroxide,dbu,nucleophile,sulfides,catalytic asymmetric oxidation
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Jun 2011 09:42
Last Modified:	24 Sep 2024 10:09
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32851
DOI:	10.1081/scc-120020208

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