An IMDA approach to tigliane and daphnane diterpenoids: Generation of rings A, B and C incorporating C-18

Bulman Page, P. C. B., Hayman, C. M., McFarland, H. L., Willock, D. J. and Galea, N. M. (2002) An IMDA approach to tigliane and daphnane diterpenoids: Generation of rings A, B and C incorporating C-18. Synlett (4). pp. 583-587. ISSN 0936-5214

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Abstract

A synthesis of the tricyclic ring system of the daphnane and tigliane diterpenes, incorporating C-18 and the C-13 oxygen functionality found in phorbol and related compounds is described. The convergent synthesis utilizes an intramolecular Diels-Alder reaction as the key stereocontrolling step.

Item Type: Article
Uncontrolled Keywords: affinity,systems,tumor promoters,daphnane,tigliane,furans imdaf,skeleton,phorbol,phorbol,model,protein-kinase-c,entry,imda,synthesis,diels-alder reactions
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jun 2011 10:18
Last Modified: 21 Apr 2020 20:43
URI: https://ueaeprints.uea.ac.uk/id/eprint/32838
DOI:

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