An IMDA approach to tigliane and daphnane diterpenoids: Generation of rings A, B and C incorporating C-18

Bulman Page, Philip C., Hayman, Colin M., McFarland, Heather L., Willock, David J. and Galea, Natasha M. (2002) An IMDA approach to tigliane and daphnane diterpenoids: Generation of rings A, B and C incorporating C-18. Synlett (4). pp. 583-587. ISSN 0936-5214

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Abstract

A synthesis of the tricyclic ring system of the daphnane and tigliane diterpenes, incorporating C-18 and the C-13 oxygen functionality found in phorbol and related compounds is described. The convergent synthesis utilizes an intramolecular Diels-Alder reaction as the key stereocontrolling step.

Item Type:	Article
Uncontrolled Keywords:	affinity,systems,tumor promoters,daphnane,tigliane,furans imdaf,skeleton,phorbol,phorbol,model,protein-kinase-c,entry,imda,synthesis,diels-alder reactions
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Jun 2011 10:18
Last Modified:	12 Sep 2023 08:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32838
DOI:	10.1055/s-2002-22700

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