Electrophilic amination of ketone enolates mediated by the DiTOX asymmetric building block: Enantioselective formal synthesis of alpha-aminoacids

Bulman Page, Philip C.., McKenzie, Michael J., Allin, Steven M. and Buckle, Derek R. (2000) Electrophilic amination of ketone enolates mediated by the DiTOX asymmetric building block: Enantioselective formal synthesis of alpha-aminoacids. Tetrahedron, 56 (49). pp. 9683-9695. ISSN 0040-4020

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Abstract

Diastereoselective electrophilic amination of enolates derived from 2-acyl-1,3-dithiane 1-oxides is used as the key step for an enantioselective synthesis of two alpha -hydrazido carboxylic acids, well-known precursors of alpha -amino acids. (C) 2000 Elsevier Science Ltd. All rights reserved.

Item Type:	Article
Uncontrolled Keywords:	arylglycines,ethers,alkylation,sulfoxidation,esters,hydrazino acids,chiral auxiliary,3-dithiane 1-oxides,acid-derivatives,1,asymmetric synthesis,aminoacid,stereoselective amination,enolate,azodicarboxylate
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Jun 2011 11:45
Last Modified:	24 Sep 2024 10:26
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32812
DOI:	10.1016/S0040-4020(00)00923-6

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