Reactivity patterns in cationic tricarbonyliron complexes: crystallographic proof of stereoselectivity in long range asymmetric induction in the 1,3/1 ',2 ' series

Anson, Christopher E., Hudson, Richard D. A., Smyth, Donald G. and Stephenson, G. Richard (2001) Reactivity patterns in cationic tricarbonyliron complexes: crystallographic proof of stereoselectivity in long range asymmetric induction in the 1,3/1 ',2 ' series. Applied Organometallic Chemistry, 15 (1). pp. 16-22. ISSN 0268-2605

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Abstract

The analysis of patterns of regioselectivity in cyclohexadienyl complexes illustrates the versatility and power of the iron-based methodology in reaction sequences that make multiple use of the metal to establish a series of chiral centres, The conversion of tricarbonyl(eta (4)-cyclohexadienone)iron(0) into the dimethyl malonate adduct 4, which contains two chiral centres at carbon besides the controlling chirality of the tricarbonyliron complex itself, provides an example of long-range asymmetric induction. The relative stereochemistry of the 1,3/1',2' product has been defined as S,S,R*,R*. Copyright (C) 2001 John Wiley & Sons, Ltd.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 08 Jun 2011 11:24
Last Modified: 21 Apr 2020 20:56
URI: https://ueaeprints.uea.ac.uk/id/eprint/31997
DOI: 10.1002/1099-0739(200101)15:1<16::AID-AOC122>3.0.CO;2-9

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