Reactivity patterns in cationic tricarbonyliron complexes: crystallographic proof of stereoselectivity in long range asymmetric induction in the 1,3/1 ',2 ' series

Anson, Christopher E., Hudson, Richard D. A., Smyth, Donald G. and Stephenson, G. Richard ORCID: https://orcid.org/0000-0003-1487-9178 (2001) Reactivity patterns in cationic tricarbonyliron complexes: crystallographic proof of stereoselectivity in long range asymmetric induction in the 1,3/1 ',2 ' series. Applied Organometallic Chemistry, 15 (1). pp. 16-22. ISSN 0268-2605

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Abstract

The analysis of patterns of regioselectivity in cyclohexadienyl complexes illustrates the versatility and power of the iron-based methodology in reaction sequences that make multiple use of the metal to establish a series of chiral centres, The conversion of tricarbonyl(eta (4)-cyclohexadienone)iron(0) into the dimethyl malonate adduct 4, which contains two chiral centres at carbon besides the controlling chirality of the tricarbonyliron complex itself, provides an example of long-range asymmetric induction. The relative stereochemistry of the 1,3/1',2' product has been defined as S,S,R*,R*. Copyright (C) 2001 John Wiley & Sons, Ltd.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	08 Jun 2011 11:24
Last Modified:	24 Oct 2022 03:32
URI:	https://ueaeprints.uea.ac.uk/id/eprint/31997
DOI:	10.1002/1099-0739(200101)15:1<16::AID-AOC122>3.0.CO;2-9

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