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Anson, Christopher E., Dave, Gaurang and Stephenson, G. Richard 
ORCID: https://orcid.org/0000-0003-1487-9178
(2000)
Stereocontrolled preparation of stereocomplementary regioisomeric tricarbonyliron complexes in enantiopure form.
Tetrahedron, 56 (15).
pp. 2273-2281.
ISSN 0040-4020
Abstract
The use of ultrasound to form ferralactone complexes from an enantiomerically pure allylic epoxide with an adjacent hydroxymethyl substituent affords a pair of stereocomplementary isomers that offer a regioconvergent route to the same chiral pentadienyliron complex. The enantiomeric purity, CD properties, and absolute configurations of intermediate eta(4)-diene complexes are reported, and X-ray diffraction analysis of a pair of rearranged ferralactone complexes establishes their relative stereochemistries, and confirms their absolute stereochemistries. (C) 2000 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Depositing User: | Rachel Smith |
| Date Deposited: | 08 Jun 2011 11:29 |
| Last Modified: | 24 Oct 2022 03:49 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/31993 |
| DOI: | 10.1016/S0040-4020(99)01110-2 |
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