Thiacalix[4]tube: synthesis, X-ray crystal structure and preliminary binding studies

Matthews, Susan E., Felix, Vitor, Drew, Michael G. B. and Beer, Paul D. (2001) Thiacalix[4]tube: synthesis, X-ray crystal structure and preliminary binding studies. New Journal of Chemistry, 25 (11). pp. 1355-1358. ISSN 1144-0546

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Abstract

The calix [4] tube family of ionophores has been extended to encompass the slightly larger thiacalix [4] tube. H-1 NMR and crystallographic studies show the ligand to adopt a flexible C-2v flattened cone arrangement. However, in contrast to the parent calix [4] tube, preliminary binding studies show no selectivity for potassium, in agreement with the absence of a template effect in tube formation and molecular modelling studies.

Item Type: Article
Uncontrolled Keywords: metal,selectivity,sulfur
Faculty \ School: Faculty of Science > School of Pharmacy
Depositing User: Rachel Smith
Date Deposited: 26 May 2011 12:01
Last Modified: 31 Oct 2019 14:07
URI: https://ueaeprints.uea.ac.uk/id/eprint/31442
DOI: 10.1039/B106094P

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