Thiacalix[4]tube: synthesis, X-ray crystal structure and preliminary binding studies

Matthews, Susan E. ORCID: https://orcid.org/0000-0001-8821-0851, Felix, Vitor, Drew, Michael G. B. and Beer, Paul D. (2001) Thiacalix[4]tube: synthesis, X-ray crystal structure and preliminary binding studies. New Journal of Chemistry, 25 (11). pp. 1355-1358. ISSN 1144-0546

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Abstract

The calix [4] tube family of ionophores has been extended to encompass the slightly larger thiacalix [4] tube. H-1 NMR and crystallographic studies show the ligand to adopt a flexible C-2v flattened cone arrangement. However, in contrast to the parent calix [4] tube, preliminary binding studies show no selectivity for potassium, in agreement with the absence of a template effect in tube formation and molecular modelling studies.

Item Type:	Article
Uncontrolled Keywords:	metal,selectivity,sulfur
Faculty \ School:	Faculty of Science > School of Pharmacy
UEA Research Groups:	Faculty of Science > Research Groups > Medicinal Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemical Biology and Medicinal Chemistry (former - to 2021)
Depositing User:	Rachel Smith
Date Deposited:	26 May 2011 12:01
Last Modified:	05 May 2024 00:49
URI:	https://ueaeprints.uea.ac.uk/id/eprint/31442
DOI:	10.1039/B106094P

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