Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin

Cammidge, Andrew N., Scaife, Peter J., Berber, Gûlen and Hughes, David L. (2005) Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin. Organic Letters, 7 (16). pp. 3413-3416.

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Abstract

[GRAPHIC] A porphyrin-ferrocene dyad has been synthesized in which there is close face-to-face contact between the two aromatic systems, providing a model for heterobimetallic polymers based on the same repeating unit. Attempts to synthesize the 2:1 adduct instead led to a remarkable intramolecular Heck-type cyclization which planarizes the system and extends the conjugation.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 09 May 2011 15:00
Last Modified: 21 Apr 2020 20:00
URI: https://ueaeprints.uea.ac.uk/id/eprint/30055
DOI: 10.1021/ol050962g

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