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Cammidge, Andrew N. 
ORCID: https://orcid.org/0000-0001-7912-4310, Scaife, Peter J., Berber, Gûlen and Hughes, David L.
(2005)
Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin.
Organic Letters, 7 (16).
pp. 3413-3416.
Abstract
[GRAPHIC] A porphyrin-ferrocene dyad has been synthesized in which there is close face-to-face contact between the two aromatic systems, providing a model for heterobimetallic polymers based on the same repeating unit. Attempts to synthesize the 2:1 adduct instead led to a remarkable intramolecular Heck-type cyclization which planarizes the system and extends the conjugation.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Depositing User: | Rachel Smith |
| Date Deposited: | 09 May 2011 15:00 |
| Last Modified: | 12 May 2023 09:30 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/30055 |
| DOI: | 10.1021/ol050962g |
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