Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin

Cammidge, Andrew N. ORCID: https://orcid.org/0000-0001-7912-4310, Scaife, Peter J., Berber, Gûlen and Hughes, David L. (2005) Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin. Organic Letters, 7 (16). pp. 3413-3416. ISSN 1523-7052

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Abstract

[GRAPHIC] A porphyrin-ferrocene dyad has been synthesized in which there is close face-to-face contact between the two aromatic systems, providing a model for heterobimetallic polymers based on the same repeating unit. Attempts to synthesize the 2:1 adduct instead led to a remarkable intramolecular Heck-type cyclization which planarizes the system and extends the conjugation.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User:	Rachel Smith
Date Deposited:	09 May 2011 15:00
Last Modified:	24 Sep 2024 09:56
URI:	https://ueaeprints.uea.ac.uk/id/eprint/30055
DOI:	10.1021/ol050962g

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