Aryl trihydroxyborates: Easily isolated discrete species convenient for direct application in coupling reactions

Cammidge, Andrew N., Goddard, Victoria H. M., Gopee, Hermant, Harrison, Nicola L., Hughes, David L., Schubert, Christopher J., Sutton, Benjamin M., Watts, Gary L. and Whitehead, Andrew J. (2006) Aryl trihydroxyborates: Easily isolated discrete species convenient for direct application in coupling reactions. Organic Letters, 8 (18). pp. 4071-4074.

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Abstract

A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the use of correct reaction stoichiometry.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 09 May 2011 14:37
Last Modified: 21 Apr 2020 19:40
URI: https://ueaeprints.uea.ac.uk/id/eprint/30048
DOI: 10.1021/ol061564w

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