Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997)

Blake, Antony B., Anson, Christopher E., arapKoske, Sam K., Cannon, Roderick D., Jayasooriya, Upali A., Saad, Ahmed K., White, Ross P. and Summerfield, Dean (2000) Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997). Dalton Transactions (12). pp. 2039-2044. ISSN 1477-9234

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Abstract

Inelastic neutron scattering measurements on the complexes [Cu4OCl6L4] (L = pyridine or dimethyl sulfoxide) revealed ground-state zero-field splittings of ca. 3 and 6 cm-1. The splittings are interpreted as due to the combined effects of exchange and spin–orbit coupling, and suggest a new interpretation of previous magnetic data.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Physical and Analytical Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	09 May 2011 11:24
Last Modified:	24 Sep 2024 10:26
URI:	https://ueaeprints.uea.ac.uk/id/eprint/29771
DOI:	10.1039/A700156H

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