Syntheses and structures of thermally stable diketiminato complexes of gold and copper

Carrera, Nora, Savjani, Nicky, Simpson, Jason, Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2011) Syntheses and structures of thermally stable diketiminato complexes of gold and copper. Dalton Transactions, 40 (5). pp. 1016-1019. ISSN 1477-9234

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Abstract

While most metallic elements across the Periodic Table form stable chelating ß-diketiminato complexes, examples of Au(I) are conspicuous by their absence. We report here the reaction of K[HC(F3CC==NR)2] with AuCl(PPh3) which provides a rare example of a thermally stable gold(I) diketiminato complex, (Ph3P)Au[RN==C(CF3)CH(CF3)C==NR] [R = 3,5-C6H3(CF3)2]. The complex is highly fluxional in solution but in the solid state adopts a U-conformation. By contrast, the analogous reaction of K[HC(F3CC==NR)2] with CuBr(PPh3)3 gives the rigid 18-electron chelate complex (Ph3P)2Cu[?2-HC{(CF3)C==NR}2]

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	12 Apr 2011 14:08
Last Modified:	23 Oct 2022 00:49
URI:	https://ueaeprints.uea.ac.uk/id/eprint/29049
DOI:	10.1039/C0DT01422B

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