The influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2: Implications for inversion analyses

Suntharalingam, Parvadha, Randerson, James T., Krakauer, Nir, Logan, Jennifer A. and Jacob, Daniel J. (2005) The influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2: Implications for inversion analyses. Global Biogeochemical Cycles, 19. ISSN 1944-9224

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Abstract

Recent inverse analyses constraining carbon fluxes using atmospheric CO2 observations have assumed that the CO2 source from atmospheric oxidation of reduced carbon is released at the surface rather than distributed globally in the atmosphere. This produces a bias in the estimates of surface fluxes. We used a three-dimensional (3D) atmospheric chemistry model (GEOS-CHEM) to evaluate the magnitude of this effect on modeled concentrations and flux estimates. We find that resolving the 3D structure of the atmospheric CO2 source, as opposed to emitting this reduced carbon as CO2 at the surface, yields a decrease in the modeled annual mean interhemispheric gradient (N-S) of 0.21 ppm. Larger adjustments (up to −0.6 ppm) are apparent on a regional basis in and downwind of regions of high reduced carbon emissions. We used TransCom3 annual mean simulations from three transport models to evaluate the implications for inversion estimates. The main impacts are systematic decreases in estimates of northern continental land uptake (i.e., by 0.22 to 0.26 Pg C yr−1), and reductions in tropical land carbon efflux with smaller changes over oceans and in the Southern Hemisphere. These adjustments represent a systematic bias in flux estimates, accounting for changes of 9 to 27% in the estimated northern land CO2 sink for the three models evaluated here. Our results highlight the need for a realistic description of reduced carbon emission and oxidation processes in deriving inversion estimates of CO2 surface fluxes.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Environmental Sciences
UEA Research Groups:	Faculty of Science > Research Groups > Centre for Ocean and Atmospheric Sciences Faculty of Science > Research Groups > Marine and Atmospheric Sciences (former - to 2017) Faculty of Science > Research Groups > Atmospheric Chemistry (former - to 2018) Faculty of Science > Research Groups > Climate, Ocean and Atmospheric Sciences (former - to 2017)
Depositing User:	Rachel Snow
Date Deposited:	12 Apr 2011 10:07
Last Modified:	17 Jan 2024 01:22
URI:	https://ueaeprints.uea.ac.uk/id/eprint/28964
DOI:	10.1029/2005GB002466

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