2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine nickel dibromides: Synthesis, characterization, and ethylene polymerization

Liu, Hao, Zhao, Weizhen, Hao, Xiang, Redshaw, Carl, Huang, Wei and Sun, Wen-Hua (2011) 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine nickel dibromides: Synthesis, characterization, and ethylene polymerization. Organometallics, 30 (8). 2418–2424.

Full text not available from this repository.

Abstract

A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines ( L1 - L5 ) and the nickel(II) dibromide complexes thereof ( C1 - C5 ) were synthesized and fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) procatalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 107 g of PE (mol of Ni)-1 h-1.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
Depositing User:	Rachel Smith
Date Deposited:	11 Apr 2011 13:50
Last Modified:	17 Jan 2024 01:20
URI:	https://ueaeprints.uea.ac.uk/id/eprint/28835
DOI:	10.1021/om200154a

Actions (login required)

View Item