Hybrid calix[4]arenes via ionic hydrogenation and transition-metal-mediated processes

Bew, Sean P. ORCID: https://orcid.org/0000-0002-9087-9463, Brimage, Rebecca A., Hiatt-Gipson, Glyn, Sharma, Sunil V. and Thurston, Sean (2009) Hybrid calix[4]arenes via ionic hydrogenation and transition-metal-mediated processes. Organic Letters, 11 (12). pp. 2483-2486. ISSN 1523-7052

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Abstract

We report the first application of ionic hydrogenation for the synthesis of upper-rim urea- or carbamate-derived hybrid calix[4]arenes. Subsequent metal-mediated transformations using 4-iodophenylurea calixarenes afforded structurally unique 1,3-di(biaryl)-, 1,3-di(biarylalkyne)-, or 1,3-(biaryl)(biarylalkyne)-derived hybrid calixarenes. © 2009 American Chemical Society.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024) Faculty of Science > School of Chemical Sciences and Pharmacy (former - to 2009) Faculty of Science
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic and Medicinal Chemistry
Related URLs:	https://www.scopus.com/pages/publication...
Depositing User:	Rachel Smith
Date Deposited:	07 Apr 2011 09:55
Last Modified:	18 Jun 2026 15:04
URI:	https://ueaeprints.uea.ac.uk/id/eprint/28347
DOI:	10.1021/ol900714n

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