Iodine speciation and deposition fluxes from the marine atmosphere

Baker, A. R. ORCID: https://orcid.org/0000-0002-8365-8953, Tunnicliffe, C. and Jickells, T. D. (2001) Iodine speciation and deposition fluxes from the marine atmosphere. Journal of Geophysical Research, 106 (D22). pp. 28743-28749. ISSN 2156-2202

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Abstract

The concentration and speciation of iodine have been determined in wet and dry deposition at a coastal site over a 15-month period. Deposition fluxes in rain (2.7 μmol m−2 yr−1) and aerosol (3.6–6.5 μmol m−2 yr−1) are the major routes for removal of iodine from the marine atmosphere onto the Earth's surface, with only a minor contribution from direct deposition of methyl iodide (0.003–0.17 μmol m−2 yr−1). Iodate (IO3−) is often considered to be the only species of iodine that is permanently removed to the aerosol phase, and IO3− may therefore be expected to be the dominant form of iodine in precipitation. However, iodide (I−) was found to constitute a significant fraction (5–100%) of iodine in both rain and aerosol. This implies that the rates of iodate formation and iodide volatilization (through reaction with hypohalous acids) are relatively slow. A third pool of aerosol iodine (nonvolatile organic compounds) may also contribute to removal of iodine from the atmosphere in dry or wet deposition.

Item Type: Article
Uncontrolled Keywords: sdg 14 - life below water ,/dk/atira/pure/sustainabledevelopmentgoals/life_below_water
Faculty \ School: Faculty of Science > School of Environmental Sciences
University of East Anglia Research Groups/Centres > Theme - ClimateUEA
UEA Research Groups: Faculty of Science > Research Groups > Centre for Ocean and Atmospheric Sciences
Faculty of Science > Research Groups > Marine and Atmospheric Sciences (former - to 2017)
Faculty of Science > Research Groups > Climate, Ocean and Atmospheric Sciences (former - to 2017)
Related URLs:
Depositing User: Rosie Cullington
Date Deposited: 30 Mar 2011 15:01
Last Modified: 11 Mar 2024 15:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/27695
DOI: 10.1029/2000JD000004

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