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ToolsHaines, Alan H. and Hughes, David L. (2010) The crystal structure of potassium (1S)-d-galactit-1-ylsulfonate. Carbohydrate Research, 345 (18). pp. 2705-2708. ISSN 1873-426X
Full text not available from this repository. (Request a copy)Abstract
The structure of the crystalline addition product formed between d-galactose and potassium bisulfite (potassium hydrogen sulfite) has been determined by X-ray diffraction analysis and compared with those structures reported for the related addition products from d-glucose and d-mannose. As with the latter two sulfonates, the d-galactose derived compound has an open-chain structure, with the carbon chain adopting a near planar zigzag conformation extending to the sulfur atom, similar to the d-mannose derivative but in contrast to the sickle conformation adopted by the d-glucose derivative. This last compound also differs in crystallising as a monohydrate. Inter-chain linking through cation coordination leads to a three dimensional network in the crystal.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| Depositing User: | Rachel Smith |
| Date Deposited: | 29 Mar 2011 12:45 |
| Last Modified: | 24 Sep 2024 09:12 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/27424 |
| DOI: | 10.1016/j.carres.2010.09.019 |
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