Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation

Yamato, Takehiko, Pérez-Casas, Carol, Yoshizawa, Akina, Rahman, Shofuir, Elsegood, Mark R. J. and Redshaw, Carl (2009) Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 63 (3). pp. 301-308. ISSN 0923-0750

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Abstract

Novel ditopic receptors of tetraamide derivatives possessing four 2-pyridyl groups derived from thiacalix[4]arene in cone- and 1,3-alternate conformation were prepared. The structure of one of the tetraamide derivatives was confirmed by a single crystal X-ray analysis. The tetrathiacalix[4]arene tetraamides show strong intramolecular hydrogen bonding. The binding behaviour towards Ag+ and halides has been investigated by 1H NMR titration experiments.

Item Type: Article
Uncontrolled Keywords: thiacalix[4]arene,o-alkylation,conformation,ionophores,hydrogen bond,metal complexation
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 29 Mar 2011 09:32
Last Modified: 10 Jan 2023 14:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/27177
DOI: 10.1007/s10847-008-9523-4

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