Vanadium procatalysts bearing chelating aryloxides: structure–activity trends in ethylene polymerisation

Redshaw, Carl (2010) Vanadium procatalysts bearing chelating aryloxides: structure–activity trends in ethylene polymerisation. Dalton Transactions, 39 (24). pp. 5595-5604. ISSN 1477-9234

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Abstract

High-valent vanadium complexes bearing a variety of chelating aryloxides including di- and linear tri-phenolates, C/N-capped tripods, phenoxyimines and calixarenes type ligands, when used in combination with dialkylaluminium halides as co-catalyst and a reactivator, are found to act as highly active catalytic systems for a-olefin polymerisation. Pro-catalyst structure–catalytic activity trends can be identified for the various ligand families employed.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
Depositing User:	Rachel Smith
Date Deposited:	29 Mar 2011 09:42
Last Modified:	15 Dec 2022 01:29
URI:	https://ueaeprints.uea.ac.uk/id/eprint/27169
DOI:	10.1039/B924088H

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