Alkylzinc Hydrazides: Self-Assembly of Hexanuclear Ring Systems in Acetonitrile

Elsegood, Mark R. J. and Redshaw, Carl (2008) Alkylzinc Hydrazides: Self-Assembly of Hexanuclear Ring Systems in Acetonitrile. Chemistry - A European Journal, 14 (12). pp. 3530-3534. ISSN 0947-6539

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Abstract

The 18th hole : Novel 18-membered zinc–nitrogen ring systems are readily accessible from the reaction of Me2NNH2 and R/R'Zn (R=R'=C6F5; R=R'=Ph; R=Et, R'=Cl) and subsequent work-up with acetonitrile. More forcing conditions are required in the case of R=R'=Et. The intriguing solid-state structures have been identified by X-ray crystallography using synchrotron radiation (see scheme), and these new complexes undergo hydrolysis to give acetamide hydrazones.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: Rachel Smith
Date Deposited: 24 Mar 2011 15:42
Last Modified: 21 Apr 2020 17:53
URI: https://ueaeprints.uea.ac.uk/id/eprint/27143
DOI: 10.1002/chem.200800183

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