Alkylzinc hydrazides: Self-assembly of hexanuclear ring systems in acetonitrile

Elsegood, Mark R. J. and Redshaw, Carl (2008) Alkylzinc hydrazides: Self-assembly of hexanuclear ring systems in acetonitrile. Chemistry - A European Journal, 14 (12). pp. 3530-3534. ISSN 0947-6539

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Abstract

The 18th hole : Novel 18-membered zinc–nitrogen ring systems are readily accessible from the reaction of Me2NNH2 and R/R'Zn (R=R'=C6F5; R=R'=Ph; R=Et, R'=Cl) and subsequent work-up with acetonitrile. More forcing conditions are required in the case of R=R'=Et. The intriguing solid-state structures have been identified by X-ray crystallography using synchrotron radiation (see scheme), and these new complexes undergo hydrolysis to give acetamide hydrazones.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
Depositing User:	Rachel Smith
Date Deposited:	24 Mar 2011 15:42
Last Modified:	16 Jan 2023 17:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/27143
DOI:	10.1002/chem.200800183

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