The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Wang, Xiufeng, Li, Zhimei, Zeng, Xirui, Luo, Qiuyan, Evans, David J., Pickett, Christopher and Liu, Xiaoming (2008) The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)? Chemical Communications (30). pp. 3555-3557. ISSN 1364-548X

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Abstract

Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	23 Mar 2011 15:49
Last Modified:	15 Dec 2022 01:32
URI:	https://ueaeprints.uea.ac.uk/id/eprint/27081
DOI:	10.1039/b805262j

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