The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Wang, Xiufeng, Li, Zhimei, Zeng, Xirui, Luo, Qiuyan, Evans, David J., Pickett, Christopher and Liu, Xiaoming (2008) The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)? Chemical Communications (30). pp. 3555-3557. ISSN 1364-548X

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Abstract

Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups: Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017)
Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User: Rachel Smith
Date Deposited: 23 Mar 2011 15:49
Last Modified: 24 Sep 2024 09:36
URI: https://ueaeprints.uea.ac.uk/id/eprint/27081
DOI: 10.1039/b805262j

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