Protonation of a subsite analogue of [FeFe]-hydrogenase: mechanism of a deceptively simple reaction revealed by time-resolved IR spectroscopy

Wright, Joseph A ORCID: https://orcid.org/0000-0001-9603-1001 and Pickett, Christopher J (2009) Protonation of a subsite analogue of [FeFe]-hydrogenase: mechanism of a deceptively simple reaction revealed by time-resolved IR spectroscopy. Chemical Communications (38). pp. 5719-5721. ISSN 1364-548X

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Abstract

We provide the first detailed time-resolved mechanistic information on the protonation of a model of the subsite of [FeFe]-hydrogenase, [Fe2(µ-pdt)(CO)4(PMe3)2]; the deceptively simple stoichiometric reaction is shown to be limited by the rate of protonation of the basal–apical isomer followed by its rearrangement to the transoid basal form.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory
Depositing User:	Rachel Smith
Date Deposited:	23 Mar 2011 15:53
Last Modified:	24 Sep 2024 09:27
URI:	https://ueaeprints.uea.ac.uk/id/eprint/27076
DOI:	10.1039/B912499C

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