Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Ibrahim, Saad, Woi, Pei Meng, Alias, Yatimah and Pickett, Christopher (2010) Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix. Chemical Communications, 46 (43). pp. 8189-8191. ISSN 1364-548X

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Abstract

We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017)
Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User: Rachel Smith
Date Deposited: 23 Mar 2011 16:05
Last Modified: 16 Dec 2023 01:39
URI: https://ueaeprints.uea.ac.uk/id/eprint/27072
DOI: 10.1039/c0cc02962a

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