Mixed cyclisations giving phthalocyanine–naphthalocyanine hybrids
Cammidge, Andrew N., Goddard, Victoria H. M., Will, Geoffrey, Arnold, Dennis P. and Cook, Michael J. (2009) Mixed cyclisations giving phthalocyanine–naphthalocyanine hybrids. Tetrahedron Letters, 50 (25). pp. 3013-3016.
Full text not available from this repository. (Request a copy)Abstract
Mixed cyclisations have been performed to give phthalocyanine–naphthalocyanine hybrids bearing solubilising substituents. Reactivity differences between the two phthalonitrile precursors result in inefficient mixed-macrocyclisation under standard, non-templating conditions leading to predominant formation of symmetrical phthalocyanine. Templated mixed-macrocyclisation leads to the hybrids. However, the reaction proceeds with unexpected selectivity with only one of the possible 2:2 products observed.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | Rachel Smith |
Date Deposited: | 22 Mar 2011 13:32 |
Last Modified: | 09 Jun 2022 13:55 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/26871 |
DOI: | 10.1016/j.tetlet.2009.03.193 |
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