Iminium salt-catalysed asymmetric epoxidation using hydrogen peroxide as stoichiometric oxidant

Bulman Page, Philip, Parker, Phillip, Rassias, Gerasimos A., Buckley, Benjamin R. and Bethell, Donald (2008) Iminium salt-catalysed asymmetric epoxidation using hydrogen peroxide as stoichiometric oxidant. Advanced Synthesis & Catalysis, 350 (11-12). pp. 1867-1874. ISSN 1615-4150

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Abstract

Iminium salt organocatalysts can provide high selectivity and high efficiency in catalytic asymmetric epoxidation. They are normally used in conjunction with Oxone as the stoichiometric oxidant. Oxone, however, has limited stability and is insoluble in most organic solvents; we report here for the first time the development of a reaction system driven by hydrogen peroxide as the stoichiometric oxidant, involving an unusual double catalytic cycle.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	22 Mar 2011 12:23
Last Modified:	24 Sep 2024 09:28
URI:	https://ueaeprints.uea.ac.uk/id/eprint/26836
DOI:	10.1002/adsc.200800303

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