Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate

Bulman Page, Philip, Marken, Frank, Williamson, Craig, Chan, Yohan, Buckley, Benjamin R. and Bethell, Donald (2008) Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate. Advanced Synthesis & Catalysis, 350 (7-8). pp. 1149-1154. ISSN 1615-4150

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Abstract

An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ees to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.

Item Type:	Article
Uncontrolled Keywords:	catalysis,electrochemistry,epoxidation,oxone,percarbonates,persulfates
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	22 Mar 2011 12:29
Last Modified:	24 Sep 2024 09:28
URI:	https://ueaeprints.uea.ac.uk/id/eprint/26834
DOI:	10.1002/adsc.200800064

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