Synthesis and structure of the dimethyl sulfide adducts of mono- and bis(pentafluorophenyl)borane

Fuller, Anna-Marie, Hughes, David, Lancaster, Simon and White, Callum M. (2010) Synthesis and structure of the dimethyl sulfide adducts of mono- and bis(pentafluorophenyl)borane. Organometallics, 29 (9). pp. 2194-2197.

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Abstract

The borane dimethyl sulfide adduct H3B·SMe2 and the diethyl ether adduct of tris(pentafluorophenyl)borane, (C6F5)3B·OEt2, undergo facile exchange of hydride and pentafluorophenyl ligands, yielding (C6F5)2HB·SMe2 ( 1 ) and (C6F5)H2B·SMe2 ( 2 ) depending upon the ratio of reagents used. In the presence of excess dimethyl sulfide, both compounds can be isolated as colorless crystals, which have been structurally characterized.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	21 Mar 2011 15:55
Last Modified:	24 Sep 2024 09:12
URI:	https://ueaeprints.uea.ac.uk/id/eprint/26782
DOI:	10.1021/om100152v

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