The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate

Martin, Eddy, Hughes, David L. and Lancaster, Simon J. (2010) The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate. Inorganica Chimica Acta, 363 (1). pp. 275-278.

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Abstract

Treatment of LiC6F5 with B(C6F5)3 in equal volumes of light petroleum and diethyl ether at low temperature followed by slow warming to room temperature precipitates a microcrystalline solid which dries under vacuum to a material with the composition [Li(OEt2)3][B(C6F5)4]. Crystallization from diethyl ether yields solvent dependent [Li(OEt2)4][B(C6F5)4], which has been crystallographically characterised.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	21 Mar 2011 16:13
Last Modified:	22 Dec 2022 17:31
URI:	https://ueaeprints.uea.ac.uk/id/eprint/26781
DOI:	10.1016/j.ica.2009.09.013

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