Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

Fuller, Anna-Marie, Clegg, William, Harrington, Ross W., Hughes, David L. and Lancaster, Simon (2008) Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands. Chemical Communications (44). pp. 5776-5778. ISSN 1364-548X

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Abstract

The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]-, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	21 Mar 2011 16:32
Last Modified:	24 Sep 2024 09:27
URI:	https://ueaeprints.uea.ac.uk/id/eprint/26773
DOI:	10.1039/B812785A

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