Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability

Redshaw, Carl, Jana, Surajit, Shang, Congxiao, Elsegood, Mark R. J., Lu, Xuesong and Guo, Zheng Xiao (2010) Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability. Organometallics, 29 (22). pp. 6129-6132.

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Abstract

Three zinc carboxylate complexes, [(C6F5Zn)4Zn(Ar1)6]·1.5toluene, [(C6F5Zn)4Zn(Ar2)6]·2toluene, and [(Ar3)6Zn4(µ4-O)]·MeCN (where Ar1 = 2-chlorobenzoic acid ( 1 ), Ar2 = 2,4,6-trimethylbenzoic acid ( 2 ), and Ar3 = 3-dimethylaminobenzoic acid ( 3 )), have been prepared from the reaction of (C6F5)2Zn·toluene and the corresponding functionalized benzoic acid. Complexes 1 - 3 were structurally characterized and screened for hydrogen absorption (uptake <0.3 wt %).

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Faculty of Science > School of Environmental Sciences
Related URLs:
Depositing User: Rachel Snow
Date Deposited: 16 Mar 2011 14:24
Last Modified: 24 Jul 2019 14:15
URI: https://ueaeprints.uea.ac.uk/id/eprint/26397
DOI: 10.1021/om100703c

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