Multinuclear zinc pentafluorobenzene carboxylates: Synthesis, characterization, and hydrogen storage capability

Redshaw, Carl, Jana, Surajit, Shang, Congxiao, Elsegood, Mark R. J., Lu, Xuesong and Guo, Zheng Xiao (2010) Multinuclear zinc pentafluorobenzene carboxylates: Synthesis, characterization, and hydrogen storage capability. Organometallics, 29 (22). pp. 6129-6132.

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Abstract

Three zinc carboxylate complexes, [(C6F5Zn)4Zn(Ar1)6]·1.5toluene, [(C6F5Zn)4Zn(Ar2)6]·2toluene, and [(Ar3)6Zn4(µ4-O)]·MeCN (where Ar1 = 2-chlorobenzoic acid ( 1 ), Ar2 = 2,4,6-trimethylbenzoic acid ( 2 ), and Ar3 = 3-dimethylaminobenzoic acid ( 3 )), have been prepared from the reaction of (C6F5)2Zn·toluene and the corresponding functionalized benzoic acid. Complexes 1 - 3 were structurally characterized and screened for hydrogen absorption (uptake <0.3 wt %).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry Faculty of Science > School of Environmental Sciences
UEA Research Groups:	Faculty of Science > Research Groups > Geosciences
Depositing User:	Rachel Snow
Date Deposited:	16 Mar 2011 14:24
Last Modified:	04 Jan 2023 13:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/26397
DOI:	10.1021/om100703c

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