Controlled scrambling in porphyrin synthesis-selective synthesis of 5,10-disubstituted porphyrins

Cammidge, A ORCID: https://orcid.org/0000-0001-7912-4310 and Ozturk, O. (2001) Controlled scrambling in porphyrin synthesis-selective synthesis of 5,10-disubstituted porphyrins. Tetrahedron Letters, 42 (2). pp. 355-358.

[thumbnail of 10.1016_S0040-4039(00)01965-1.pdf]
Preview
PDF (10.1016_S0040-4039(00)01965-1.pdf)
Download (88kB) | Preview

Abstract

Condensation of phenyldipyrromethane with bisnaphthaldehyde 3 leads to unexpected formation of the scrambled 5,10-bridged porphyrin 5; this unprecedented selectivity suggests that an alternative scrambling mechanism to dipyrromethane acidolysis is operating.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User: Rachel Smith
Date Deposited: 22 Dec 2010 15:06
Last Modified: 21 Dec 2024 00:44
URI: https://ueaeprints.uea.ac.uk/id/eprint/10998
DOI: 10.1016/S0040-4039(00)01965-1

Downloads

Downloads per month over past year

Actions (login required)

View Item View Item